milbemycin oxime

French: oxime de milbémycineRussian: милбемицин оксим


Status: none
PIN:
IUPAC: extended von Baeyer nomenclature: mixture of 70% (10E,14E,16E)-(1R,4S,5′S,6R,6′R,8R,13R,20R,24S)-6′-ethyl-24-hydroxy-5′,11,13,22-tetramethyl-(3,7,19-trioxatetracyclo[15.6.1.14,8.020,24]pentacosa-10,14,16,22-tetraene)-6-spiro-2′-(tetrahydropyran)-2,21-dione 21-(EZ)-oxime and 30% (10E,14E,16E)-(1R,4S,5′S,6R,6′R,8R,13R,20R,24S)-24-hydroxy-5′,6′,11,13,22-pentamethyl-(3,7,19-trioxatetracyclo[15.6.1.14,8.020,24]pentacosa-10,14,16,22-tetraene)-6-spiro-2′-(tetrahydropyran)-2,21-dione 21-(EZ)-oxime
or
bridged fused ring systems nomenclature: mixture of 70% (2aE,4E,8E)-(5′S,6R,6′R,11R,13R,15S,17aR,20aR,20bS)-6′-ethyl-3′,4′,5′,6′,10,11,14,15,20a,20b-decahydro-20b-hydroxy-5′,6,8,19-tetramethylspiro[11,15-methano-2H,13H,17H-furo[4,3,2-pq][2,6]benzodioxacyclooctadecin-13,2′-[2H]pyran]-17,20(6H,17aH)-dione 20-(EZ)-oxime and 30% (2aE,4E,8E)-(5′S,6R,6′R,11R,13R,15S,17aR,20aR,20bS)-3′,4′,5′,6′,10,11,14,15,20a,20b-decahydro-20b-hydroxy-5′,6,6′,8,19-pentamethylspiro[11,15-methano-2H,13H,17H-furo[4,3,2-pq][2,6]benzodioxacyclooctadecin-13,2′-[2H]pyran]-17,20(6H,17aH)-dione 20-(EZ)-oxime
CAS: (6R,25R)-5-demethoxy-28-deoxy-6,28-epoxy-25-ethyl-5-(hydroxyimino)milbemycin B mixture with (6R,25R)-5-demethoxy-28-deoxy-6,28-epoxy-5-(hydroxyimino)-25-methylmilbemycin B
Reg. No.:
Formula: C31H43NO7 + C32H45NO7
Activity: acaricides (milbemycin acaricides)
insecticides (milbemycin insecticides)
Notes: There is no ISO common name for this substance; the name “milbemycin oxime” has been used in the literature but it has no official status.
Structure: Structural formula of milbemycin oxime
Pronunciation: mǐl-bě--sǐn ǒk-sēm  Guide to British pronunciation
InChIKey: 6′-ethyl:
YCAZFHUABUMOIM-OWOPNLEVSA-N
6′-methyl:
VDBGCWFGLMXRIK-FJZHFHHPSA-N
identifier for mixture (not valid):
CKVMAPHTVCTEMM-GSYGMDRSSA-N
InChI: 6′-ethyl:
InChI=1S/C32H45NO7/c1-6-27-21(4)12-13-31(40-27)17-25-16-24(39-31)11-10-20(3)14-19(2)8-7-9-23-18-37-29-28(33-36)22(5)15-26(30(34)38-25)32(23,29)35/h7-10,15,19,21,24-27,29,35-36H,6,11-14,16-18H2,1-5H3/b8-7+,20-10+,23-9+,33-28?/t19-,21-,24+,25-,26-,27+,29+,31+,32+/m0/s1
6′-methyl:
InChI=1S/C31H43NO7/c1-18-7-6-8-23-17-36-28-27(32-35)21(4)14-26(31(23,28)34)29(33)37-25-15-24(10-9-19(2)13-18)39-30(16-25)12-11-20(3)22(5)38-30/h6-9,14,18,20,22,24-26,28,34-35H,10-13,15-17H2,1-5H3/b7-6+,19-9+,23-8+,32-27?/t18-,20-,22+,24+,25-,26-,28+,30-,31+/m0/s1

A data sheet from the Compendium of Pesticide Common Names